Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
Count the valence electrons of diborane, . How many would an ethane-like structure with seven two-electron bonds need? Diborane has four terminal bonds: how many electrons are left for each of the two bridges?
A molecule with an odd number of valence electrons keeps one unpaired electron and is paramagnetic. Diborane has valence electrons: four terminal bonds and two three-centre two-electron bridges.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. Count. .
Step 2. Ethane-like. Seven bonds of two electrons each need , two more than there are.
Step 3. Bridges. Four terminal bonds use , so are left: for each bridge, spread over three atoms.
Answer: ; ; electrons in each three-centre bridge.
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