Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
Arrange MgO, CaO, NaF and KBr in order of decreasing lattice enthalpy. Give a reason for each step.
Born-Haber cycle: enthalpy of formation sublimation half the bond enthalpy ionisation enthalpy electron gain enthalpy lattice enthalpy. The lattice enthalpy is the energy needed to separate one mole of an ionic solid into its gaseous ions. It grows with the charges of the ions and as the ions get smaller.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. Charges. MgO and CaO have ions with charges of 2. NaF and KBr have charges of 1. The first pair has much larger lattice enthalpies.
Step 2. MgO and CaO. is smaller than , so MgO comes first.
Step 3. NaF and KBr. and are both smaller than and , so NaF comes before KBr.
Answer: MgO, then CaO, then NaF, then KBr.
Log in to join the discussion.
Loading…
With Standard, you also open 11 more problems, 2 Python labs and 1 extra course. Everything you have used here stays free, always.