Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
An octahedral ion has seven d electrons. Take and . Find the total energy of the high spin arrangement and of the low spin arrangement, from the average level, and the number of unpaired electrons in the more stable one.
Total energy . Octahedral: . Tetrahedral: , with . and .
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. High spin. has . It has no extra pairs.
Step 2. Low spin. has . It has 3 pairs and the free ion has 2, so 1 extra pair costs . The total is .
Step 3. The winner. The high spin total is lower by . This agrees with .
Step 4. Unpaired electrons. The high spin ion has . The part has 1 unpaired electron and has 2, so there are 3 in all.
Answer: , and 3 unpaired electrons.
Log in to join the discussion.
Loading…