Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
The splitting of some hydrated ions is, in : 12400, 8500 and 7800. All are high spin. One is . Find the CFSE of () and of () in kJ/mol. How many of the three ions have zero CFSE?
Total energy . Octahedral: . Tetrahedral: , with . and .
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. Vanadium. is , so . In kJ/mol that is .
Step 2. Nickel. is , so .
Step 3. Manganese. is . In a weak field it is , so . One ion has zero CFSE.
Answer: , and 1 ion. Vanadium gains more in size than nickel here because it has the larger splitting.
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