Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
A solution has of potassium sulphate, , of molar mass , in of water. Its freezing point is . Find the van’t Hoff factor and the degree of dissociation.
The van’t Hoff factor is . For a solute that gives ions, . For a solute that joins in pairs, . Then and .
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Given. , so one unit gives and . The measured fall is .
Step 1. Molality. in , so .
Step 2. The fall if nothing split. .
Step 3. The factor. .
Step 4. The degree of dissociation. We want , so .
Answer: , and of the salt is split into ions.
Check. The value of lies between and , as it must.
Log in to join the discussion.
Loading…