A gas has two specific heats, and the one at constant pressure is the larger. A gas that is compressed quickly gets hot, and a gas that is compressed slowly does not. In this course we find Mayer's relation, and we study the isobaric, isochoric, isothermal and adiabatic processes with the heat, work and change of internal energy of each.
3 lessons, about 1 h 10 min3 simulations12 problems6 practice questionsPython in every lesson
A gas has two molar heat capacities: at a steady volume and at a steady pressure. is larger because the gas also does work as it expands, and Mayer's relation gives . For a monatomic gas , ; for a diatomic gas , .
In an isothermal process the temperature is steady, so and . In an isobaric process the pressure is steady: and . In an isochoric process the volume is steady: and .
In an adiabatic process no heat flows: the gas is insulated or the change is too quick. Then , and and stay the same. A gas squeezed adiabatically warms, as in a diesel engine; one that expands adiabatically cools. On a pressure-volume graph an adiabat is steeper than an isotherm.
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