Match each cell in List-I, at 298K, with its emf in List-II. Each emf is for the cell as written, with the left electrode as the anode, so a negative value means the cell really runs the other way. Use NCERT's values: E∘(Mg2+/Mg)=−2.36V, E∘(Ag+/Ag)=0.80V, E∘(Sn2+/Sn)=−0.14V and E∘(Pb2+/Pb)=−0.13V, with F2.303RT=0.059V. Concentrations are in mol L−1. In every cell the solutions behave ideally, and each gas is at the pressure shown.
List-I
(P) Mg∣Mg2+(0.0010)∥Ag+(0.100)∣Ag
(Q) Pt∣H2(1bar)∣H+(pH3.00)∥H+(pH1.00)∣H2(1bar)∣Pt
(R) Sn∣Sn2+(1.00)∥Pb2+(0.0010)∣Pb
(S) Cu∣Cu2+(0.0100)∥Cu2+(1.00)∣Cu
List-II
(1) 0.06V
(2) 3.19V
(3) −0.08V
(4) 0.12V
(5) 0.10V