Assertion (A): A student adds HI to propene, CH3CH=CH2, in the presence of benzoyl peroxide, expecting the same peroxide effect as with HBr. The main product is 1-iodopropane, CH3CH2CH2I, formed against Markovnikov's rule.
Reason (R): The H−I bond, with a bond enthalpy of 296.8kJ mol−1, is weaker than the H−Br bond, 363.7kJ mol−1, while the H−Cl bond, 430.5kJ mol−1, is the strongest of the three.