Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
A sample of of ozonised oxygen at and is ozone by volume. The sample is passed through an excess of potassium iodide solution, and iodine forms by . Take as the molar volume, as the molar mass of iodine and as the standard enthalpy of formation of ozone. Find the amount of ozone, the mass of iodine, and the heat that was taken in to make this ozone from oxygen.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. Moles of gas. .
Step 2. Ozone. .
Step 3. Iodine. One mole of ozone gives one mole of iodine, so of . The mass is .
Step 4. Heat. is taken in.
Answer: of ozone, of iodine and .
Check. The ozone has a volume of , and .
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Ozone gives one mole of iodine for each mole of ozone with potassium iodide. Roasting pyrites follows 4FeS2 + 11O2 giving 2Fe2O3 + 8SO2, so each FeS2 gives 2 SO2. Permanganate and dichromate oxidise sulphur dioxide: 5 SO2 for each 2 and 3 SO2 for each . Work in moles: the amount of a solute is the volume in litres times the concentration.
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