Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
A plant burns of ammonia each day in the Ostwald process. The overall yield, from ammonia to nitric acid, is . Take the molar masses as NH3 and HNO3 . The acid is sold as a solution by mass. Find the mass of pure nitric acid, the mass of solution, and the mass of ammonia that is not turned into acid.
Oxidation states of nitrogen run from to . Nitric acid is reduced to NO2 when concentrated and to NO, N2O or NH4+ when dilute. Count electrons: a metal atom that gives up electrons needs electrons to be taken by the nitrogen. At 273 K and 1 atm, 1 mol of gas fills 22.4 L. The Ostwald process gives 1 mol of HNO3 for each mole of NH3 at a full yield.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Given. of ammonia, a yield of .
Step 1. Moles. of ammonia.
Step 2. Acid at a full yield. One mole of ammonia gives one mole of nitric acid, so .
Step 3. At 94 percent. of pure acid.
Step 4. The solution. .
Step 5. Ammonia lost. of ammonia is not turned into acid.
Answer: of pure acid, of solution and of ammonia lost.
Check. The mass ratio gives at a full yield.
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