A brief note on Electron Shells and Valency . Read it before a test. Try each question at the end before you open its answer.
The rules Shell n n n holds at most 2 n 2 2n^2 2 n 2 electrons: K 2 2 2 , L 8 8 8 , M 18 18 18 , N 32 32 32 . The outermost shell holds at most 8 8 8 . Fill the shells from the inside. Valency: with 1 1 1 to 4 4 4 outer electrons, the valency is that number; with 5 5 5 to 7 7 7 , it is 8 8 8 minus it; a full shell gives 0 0 0 . Atomic number Z Z Z = protons. Mass number A A A = protons + neutrons. Neutrons = A − Z = A - Z = A − Z . In a neutral atom, electrons = Z = Z = Z . An ion has the same nucleus, with the electrons changed by the charge. Some atoms at a glance Atom Z Z Z Arrangement Valency Ion Lithium 3 3 3 2 , 1 2, 1 2 , 1 1 1 1 Li + \text{Li}^+ Li + Fluorine 9 9 9 2 , 7 2, 7 2 , 7 1 1 1 F − \text{F}^- F − Neon 10 10 10 2 , 8 2, 8 2 , 8 0 0 0 none Phosphorus 15 15 15 2 , 8 , 5 2, 8, 5 2 , 8 , 5 3 3 3 P 3 − \text{P}^{3-} P 3 − Potassium 19 19 19 2 , 8 , 8 , 1 2, 8, 8, 1 2 , 8 , 8 , 1 1 1 1 K + \text{K}^+ K +
A worked example An atom has the mass number 19 19 19 and 10 10 10 neutrons. Find its atomic number, its arrangement, its valency and its ion.
Atomic number. Z = 19 − 10 = 9 Z = 19 - 10 = 9 Z = 19 − 10 = 9 . It is fluorine. Arrangement. 9 9 9 electrons: 2 , 7 2, 7 2 , 7 . Valency. 8 − 7 = 1 8 - 7 = 1 8 − 7 = 1 . Ion. It gains 1 1 1 electron: F − \text{F}^- F − , with 10 10 10 electrons. Practice with new numbers
A program to try The program finds the arrangement and the valency for six atomic numbers.
Read it, then run it. Which atom in the list has a valency of 0 0 0 ?
1. Add 20 20 20 to the list. What are the arrangement and the valency of calcium?
Mistakes to avoid Putting more than 8 8 8 in the outer shell , as in 2 , 8 , 9 2, 8, 9 2 , 8 , 9 for potassium. Taking the outer electrons as the valency when there are more than 4 4 4 . Using A A A as the number of protons. Protons are Z Z Z . Changing the protons of an ion. Only the electrons change. Check yourself Write the electron arrangement of phosphorus, Z = 15 Z = 15 Z = 15 . Stuck? Show a hint Show the answerWhat is the valency of an atom with the arrangement 2 , 3 2, 3 2 , 3 ? Stuck? Show a hint Show the answerHow many neutrons are there in 26 56 Fe {}^{56}_{26}\text{Fe} 26 56 Fe ? Stuck? Show a hint Show the answerAn ion X 2 + \text{X}^{2+} X 2 + has 18 18 18 electrons. What is the atomic number of X? Stuck? Show a hint Show the answer