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  1. Glossary
  2. /Chemistry
  3. /Ionic Radius

What is Ionic Radius?

In short

The ionic radius is the size of an ion in an ionic crystal. A positive ion is smaller than its atom, and a negative ion is larger than its atom.

In simple words

A cation loses electrons, so the electrons that remain are pulled more strongly by the nucleus, and the ion shrinks. An anion gains electrons, and the extra repulsion makes it swell. For ions with the same number of electrons (isoelectronic), the one with the larger nuclear charge is smaller. Down a group, ionic size rises.

Example

Na+\text{Na}^+Na+ and F−\text{F}^-F− both have 10 electrons. Sodium has 11 protons and fluorine has 9, so Na+\text{Na}^+Na+ (102 pm102\ \text{pm}102 pm) is smaller than F−\text{F}^-F− (133 pm133\ \text{pm}133 pm).

Also searched as: ionic size, molecule sizes.

Learn it properly

  • Lessons on this topic
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Related terms

  • Periodic Trends
  • Ionisation Enthalpy

← All glossary terms

Learn it in

  1. Patterns Across Periods and Down GroupsClass 9 to 10
  2. Periodic Trends in PropertiesClass 11 to 12
All lessons on this topic →

Practise

  1. On the Pauling scale sodium is 0.9, hydrogen 2.1, carbon 2.5 and chlorine 3.0…Hard
  2. Sodium oxide, aluminium oxide and sulphur trioxide are each tested with water, with…Medium
  3. Use the valences of the groups to write three formulas…
Easy
  • The electron gain enthalpy of chlorine is -349 kJ mol⁻¹ and that of fluorine -328 kJ…Hard
  • All problems on this topic →

    Quick questions

    1. Consider the period 3 oxides SiO₂, Cl₂O₇, Na₂O, P₄O₁₀ and Al₂O₃. Each oxide is treated…Hard
    2. Consider these ten oxides: BeO, MgO, B₂O₃, Ga₂O₃, ZnO, SnO₂, CO, Cr₂O₃, CrO₃ and Mn₂O₇.…Advanced
    3. Red lead, Pb₃O₄ (molar mass 685.6 g mol⁻¹), is a mixed oxide that contains lead in two…Hard

    More Chemistry terms

    1. Metalloid
    2. Electronegativity
    3. Acids, Bases and pH
    4. Alkane (Saturated Hydrocarbon)
    5. Allotrope
    6. Atom
    All Chemistry terms →

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