In short
Hybridisation is the mixing of atomic orbitals of one atom to form new, equivalent hybrid orbitals that are used for bonding. It explains the shapes of molecules such as methane.
Carbon in methane has the configuration , but it forms four equal bonds. One and three orbitals mix to make four orbitals pointing to the corners of a tetrahedron, at . Mixing one and two gives three orbitals in a plane at , and one with one gives two orbitals in a line at .
Ethene, , is planar. Each carbon is hybridised, with a bond angle of about .
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