How the size of atoms and ions, the ionisation enthalpy, the electron gain enthalpy and the electronegativity change across a period and down a group, and how they decide valence and reactivity.
3 lessons, about 1 h 25 min3 simulations11 problems5 practice questionsPython in every lesson
Atoms get smaller across a period and larger down a group. A cation is smaller than its atom, and an anion larger. In a set of isoelectronic species, the one with the most protons is the smallest. The covalent radius is half the distance between two bonded nuclei.
Ionisation enthalpy is the energy to remove the outermost electron from a gaseous atom. It rises across a period, with dips at groups 13 and 16, and falls down a group. Electron gain enthalpy is the enthalpy change when a gaseous atom takes an electron, most negative for the halogens.
Electronegativity measures how strongly an atom in a molecule pulls a shared pair of electrons. It rises across a period and falls down a group. The trends explain valence, the unusual second period, the diagonal relationship, chemical reactivity and why oxides change from basic to acidic across a period.
Log in to join the discussion.
Loading…