Many enzyme reactions follow the rate law −dtd[S]=Km+[S]Vmax[S], where S is the substance the enzyme acts on. This rate is nearly zero order when [S] is much larger than Km, and nearly first order when [S] is much smaller. For one enzyme at a fixed temperature, Vmax=1.00×10−3 mol L−1 min−1 and Km=5.00×10−3 mol L−1. The amount of enzyme stays constant. A solution starts with [S]0=2.00×10−2 mol L−1. How long does it take for [S] to fall to 5.00×10−3 mol L−1? Give the answer in min, to two decimal places. Take ln2=0.6931.