Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
The blue complex is tetrahedral. The atomic number of cobalt is 27. (a) Write the arrangement of the d electrons of as the numbers in the and sets. (b) How many electrons are unpaired, and what is the spin-only moment? (c) Is a low spin arrangement likely? Give a reason.
In an octahedral field the set lies at and the set at . A d electron count of 4 to 7 gives high spin if and low spin if . In a tetrahedral field the set lies at and the set at , with . in an octahedron.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. The electrons. has electrons in 3d. The lower set takes four of them, two in each orbital. The three orbitals take the other three, one each. The arrangement is .
Step 2. Unpaired electrons. The three electrons are unpaired. So and .
Step 3. Low spin? No. The gap is , less than half the octahedral gap, and it is smaller than the pairing energy. The electrons spread over all five orbitals instead of pairing.
Answer: with 3 unpaired electrons and a moment of . A low spin form is not likely.
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