Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
Sulphur dioxide is oxidised in air by a mechanism with two steps. Step 1, slow: . Step 2, fast: . Name the catalyst and the intermediate. Write the overall equation. What is the rate law if the first step is slow?
A catalyst lowers the barrier by in both directions. If stays the same, . and the equilibrium constant do not change. In a mechanism, a catalyst is used in one step and made again in a later one.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. Add the steps. Double step 1: . Add step 2: . The and the cancel. What remains is .
Step 2. The catalyst. is there at the start, used in step 1 and made again in step 2. It is the catalyst.
Step 3. The intermediate. is made in step 1 and used up in step 2. It is the intermediate.
Step 4. The rate law. The slow step sets the rate, and it is a collision of with . So . The catalyst is in the rate law though not in the overall equation.
Answer: is the catalyst and is the intermediate. The overall equation is and the rate law is .
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