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  1. Problems
  2. /Hydrogen atoms jump between the first eight levels, in every possible way…
MediumPhysicsHigh School (11–12)Modern Physics › Atoms and Atomic SpectraAtomic PhysicsNumericalpythonNEETAPA-LevelIBAEEE (Amrita)AMUEEE
+18 more exams
AP EAPCETBCECECOMEDK UGETCUET UGGUJCETJCECEJKCETKCETKEAMKIITEELPUNESTMET (Manipal)MHT-CETOJEESRMJEEE

Hydrogen atoms jump between the first eight levels, in every possible way…

StemPy LabContributed by StemPy Lab

Try it on paper first. A hint, the key idea and the worked solution are here when you need them.

Hydrogen atoms jump between the first eight levels, in every possible way. Find the jumps that give light with a wavelength between 400 nm400\ \text{nm}400 nm and 700 nm700\ \text{nm}700 nm. How many are there? What are the shortest and the longest wavelength among them? Take R=1.097×107 m−1R = 1.097 \times 10^7\ \text{m}^{-1}R=1.097×107 m−1.

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Work it out on paper, then type your number. The answer itself stays hidden.

nm
nm
Need a reminder? The key ideaShowHide
1λ=RZ2(1nf2−1ni2)R=1.097×107 m−1\displaystyle \frac{1}{\lambda} = RZ^2\left(\frac{1}{n_f^2} - \frac{1}{n_i^2}\right) \qquad R = 1.097 \times 10^7\ \text{m}^{-1}λ1​=RZ2(nf2​1​−ni2​1​)R=1.097×107 m−1

The limit of a series has ni→∞n_i \to \inftyni​→∞.

The worked solution

Have you tried it?

Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.

Step 1. Which series. A jump that ends on n=1n = 1n=1 gives ultraviolet. Jumps that end on n=3n = 3n=3 or higher give infrared. So we try nf=2n_f = 2nf​=2.

Step 2. The jumps. With 1λ=R(14−1ni2)\dfrac{1}{\lambda} = R\left(\dfrac{1}{4} - \dfrac{1}{n_i^2}\right)λ1​=R(41​−ni2​1​):

  • 3→23 \to 23→2: 656 nm656\ \text{nm}656 nm
  • 4→24 \to 24→2: 486 nm486\ \text{nm}486 nm
  • 5→25 \to 25→2: 434 nm434\ \text{nm}434 nm
  • 6→26 \to 26→2: 410 nm410\ \text{nm}410 nm
  • 7→27 \to 27→2: 397 nm397\ \text{nm}397 nm, just outside the range.

Step 3. Answer. There are 4 visible lines, from 410 nm410\ \text{nm}410 nm to 656 nm656\ \text{nm}656 nm.

What if? In a hotter gas, atoms start at higher levels, but the extra Balmer lines are all violet or ultraviolet.

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