Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
Aqua regia is made by mixing of concentrated hydrochloric acid () with of concentrated nitric acid (). Gold dissolves by the reaction . Take the molar mass of gold as . Find the moles of each acid, the largest mass of gold the mixture can dissolve, the volume of NO at and , and the moles of nitric acid left over.
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Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Plan. Compare how much gold each acid could dissolve, and take the smaller.
Step 1. Moles. HCl: . HNO3: .
Step 2. The limit. HCl could dissolve of gold. HNO3 could dissolve . So hydrochloric acid limits.
Step 3. Gold. .
Step 4. Nitric oxide. of NO has a volume of .
Step 5. Nitric acid left. .
Answer: , of gold, of NO and of nitric acid left.
Check. The ratio of the acids in the mixture is 3 : 1 by volume, but the amounts are . The nitric acid is in excess.
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In an interhalogen compound or a xenon compound, count the lone pairs on the central atom. The number is the outer electrons minus the electrons used in bonds, divided by 2. The steric number is the bonded atoms plus the lone pairs. A weak acid with constant and concentration gives with , and .
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