Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
A student warms 1.605 g of ammonium chloride, , with an excess of sodium hydroxide solution in a test tube. A glass rod dipped in concentrated hydrochloric acid, held at the mouth of the tube, gives dense white fumes. Use N = 14, H = 1 and Cl = 35.5 in g/mol. Find the amount of ammonia, its volume at 273 K and 1 atm, and its mass.
The group scheme is: zero ; I ; II ; III , ; IV , , , ; V , ; VI . Zinc, aluminium and lead hydroxides dissolve in excess sodium hydroxide. Copper, nickel, zinc and cobalt hydroxides dissolve in excess ammonium hydroxide as ammines. Iron(III) and hexacyanoferrate(II) make Prussian blue: .
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. , so . The ammonia is .
Step 2. .
Step 3. , so .
Answer: , and .
Check. The white fumes are ammonium chloride again: .
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