Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
A student mixes of benzene () with of ethanoyl chloride () and equivalents of anhydrous aluminium chloride () for each mole of the acid chloride. The yield of acetophenone () is . Find the amount of the limiting reagent, the theoretical mass of acetophenone, the mass obtained and the mass of aluminium chloride.
Etard: toluene, CrOCl in CS, then HO. Gattermann-Koch: benzene, CO, HCl, anhydrous AlCl and CuCl. Friedel-Crafts acylation: benzene, an acyl chloride and anhydrous AlCl, which is needed in a little more than one mole for each mole of acyl chloride. The overall yield of a route is the product of the step yields.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. Moles. Benzene: . Ethanoyl chloride: . The acid chloride is limiting, so the limiting amount is .
Step 2. Theory. .
Step 3. Actual. .
Step 4. Aluminium chloride. .
Answer: , , and .
Check. The aluminium chloride is larger than the ketone, in mass, because the ketone holds it.
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