Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
A student has the two beakers shown in the figure. Beaker A holds of sulfuric acid. Beaker B holds of sodium hydroxide solution. She pours both into a large beaker C and stirs, taking care that nothing splashes out. The temperature stays close to room temperature. The reaction is . A friend says that the base must be in excess, simply because beaker B holds more moles than beaker A. Decide with the balanced equation, not with this shortcut. Then find out what beaker C holds at the end. Assume the volumes add, so beaker C holds , and that nothing else reacts. Atomic masses in : H 1, O 16, Na 23, S 32.
Have you tried it?
Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Given. A: of . B: of . C: after mixing.
Step 1. Moles in each beaker. Acid: . Base: .
Step 2. The limiting reagent. The acid needs of . There is , more than enough. So the acid is used up and sodium hydroxide is in excess. The friend is right this time, but for the wrong reason. Left: of .
Step 3. Its molarity. .
Step 4. Sodium sulfate. One mole of acid gives one mole of salt: . Molarity: .
Step 5. Sodium ions. All of sodium from beaker B is still there, in the salt and in the leftover base. Molarity: .
Step 6. The dry solid. Sodium sulfate (): . Sodium hydroxide (): . Total: .
Answer: (a) Sodium hydroxide; . (b) . (c) . (d) . (e) .
Check. Count the sodium two ways. In the salt and the base: , the same as in (d).
Watch out. The acid has fewer moles than the base, but that alone does not make it limiting. Had beaker B held only of base, still more than the acid, the base would have run out first. Here the acid is limiting because it needs twice its own moles of base, and is less than .
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