Try it on paper first. A hint, the key idea and the worked solution are here when you need them.
A scientist grows a plant with water in which every oxygen atom is the heavy kind, marked . The carbon dioxide is ordinary. The plant carries out photosynthesis for some hours. Use the equation for molecules of the heavy water. (a) How many heavy oxygen atoms are in the oxygen gas that is released? (b) How many are in the glucose? (c) Where do the oxygen atoms of the new water molecules come from?
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Work it out on paper first. It is fine to get stuck or make a mistake: that is how we learn. When you are ready, go through the solution one step at a time, and check each step against your own.
Step 1. The oxygen gas. All water molecules are split. Each gives one oxygen atom, so the gas holds heavy atoms (six molecules of ).
Step 2. The glucose. Glucose gets its six oxygen atoms from carbon dioxide, which is ordinary. It holds heavy atoms.
Step 3. The new water. Six carbon dioxide molecules hold oxygen atoms. Six go into glucose, and six go into the new water molecules. So the new water has ordinary oxygen.
Answer: (a) atoms; (b) atoms; (c) from carbon dioxide.
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Priestley (1770): a mint plant restores the air that a burning candle or an animal makes unfit. Ingenhousz (1779): sunlight is needed and only green parts release oxygen. Sachs (1854): glucose is made in green parts and stored as starch. Engelmann: bacteria gather in the blue and red regions of a prism spectrum, the first action spectrum. Van Niel: bacteria using H2S give out sulphur; in green plants the donor is water, so the oxygen comes from water. Overall: . Water is oxidised, carbon dioxide is reduced.
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