Why we believe matter is made of molecules, and how far apart they are in solids, liquids and gases. The gas laws of Boyle, Charles and Avogadro lead to the ideal gas equation, with moles and the Boltzmann constant. Then Dalton's law of partial pressures, and where a real gas stops being ideal.
3 lessons, about 1 h 30 min3 simulations12 problems6 practice questionsPython in every lesson
Matter is made of tiny particles called atoms and molecules. An atom is about m across. In solids and liquids the molecules nearly touch. In a gas at room conditions they are about ten times their own size apart. Brownian motion shows that the molecules never stop moving.
Boyle's law, Charles's law and Avogadro's law join into one equation for a gas at low density: , with J/(mol K) and J/K. Temperature is always in kelvin, and pressure is the absolute pressure. For a fixed amount of gas, stays the same.
In a mixture of gases, each gas pushes on the walls as if it were alone. Its share of the pressure is its partial pressure, and the total pressure is the sum of the partial pressures (Dalton's law). A real gas behaves like an ideal gas at low pressure and high temperature. At high pressure the size of the molecules and the pull between them make it differ.
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